Anion effect controlling the selectivity in the zinc-catalysed copolymerisation of CO2 and cyclohexene oxide
نویسندگان
چکیده
The choice of the anion has a surprisingly strong effect on the incorporation of CO2 into the polymer obtained during the zinc-catalysed copolymerisation of CO2 and cyclohexene oxide. The product span ranges from polyethercarbonates, where short polyether sequences alternate with carbonate linkages, to polycarbonates with a strictly alternating sequence of the repeating units. Herein, we report on the influence of the coordination ability of the anion on the selectivity and kinetics of the copolymerisation reaction.
منابع مشابه
A Lewis acid β-diiminato-zinc-complex as all-rounder for co- and terpolymerisation of various epoxides with carbon dioxide.
A β-diiminato-zinc-N(SiMe3)2 complex (1) was synthesised and fully characterised, including an X-ray diffraction study. The activity of catalyst 1 towards the coupling reaction of CO2 and various epoxides, including propylene oxide (PO), cyclohexene oxide (CHO), styrene oxide (SO), limonene oxide (LO), octene oxide (OO) and epichlorohydrin (ECH), was investigated. Terpolymerisation of CO2, PO a...
متن کاملA bimetallic iron(III) catalyst for CO2/epoxide coupling.
A novel di-iron(III) catalyst for the copolymerisation of cyclohexene oxide and CO(2) to yield poly(cyclohexene carbonate), under mild conditions, is reported. The catalyst selectivity was completely changed on addition of an ammonium co-catalyst to yield only the cis-isomer of the cyclic carbonate, also under mild conditions. Additionally, the catalyst was active for propylene carbonate and st...
متن کاملThe study of humidity effect on carbon dioxide gas sensing properties of zinc oxide nanowires assisted by polyvinyl alcohol network at room temperature
In this research, Zinc oxide (ZnO) nanostructures were synthesized by low cost hydrothermal method. The grown ZnO nanostructures had a dispersed distribution with nanowire morphology and the specific surface area of about 7 m2.gr-1 which they have crystalized in hexagonal wurtzite structure. ZnO nanowires/polyvinyl alcohol network (ZP) on the epoxy glass substrate with cu-interdigited electrods...
متن کاملSolventless Coupling of Epoxides and CO2 in Compressed Medium Catalysed by Fluorinated Metalloporphyrins
Metal complexes of meso-arylporphyrins (Cr(III), Fe(III), and Zn(II)) were evaluated in the coupling reaction of cyclohexene oxide (CHO) with CO2 in compressed medium, where the Cr complexes were demonstrated to be the most active systems, leading predominantly to copolymerisation products. It is noteworthy that no addition of solvent was required. To improve the catalytic activity, and to simu...
متن کاملDi‐Zinc–Aryl Complexes: CO2 Insertions and Applications in Polymerisation Catalysis
Two new di-zinc-aryl complexes, [LZn2 Ph2 ] and [LZn2 (C6 F5 )2 ], coordinated by a diphenol tetraamine macrocyclic ligand have been prepared and fully characterised, including by single-crystal X-ray diffraction experiments. The complexes' reactivities with monomers including carbon dioxide, cyclohexene oxide, phthalic anhydride, isopropanol and phenol were investigated using both experimental...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 11 شماره
صفحات -
تاریخ انتشار 2015